Methods of forming integrated circuits

ABSTRACT

A method of forming an integrated circuit includes forming a gate structure over a substrate. Portions of the substrate are removed to form recesses adjacent to the gate structure. A dopant-rich layer having first type dopants is formed on a sidewall and a bottom of each of the recesses. A silicon-containing material structure is formed in each of the recesses. The silicon-containing material structure has second type dopants. The second type dopants are opposite to the first type dopants.

CROSS-REFERENCES TO RELATED APPLICATIONS

The present application is related to U.S. Application Ser. No. 61/418,105, entitled “METHODS OF FORMING INTEGRATED CIRCUITS” filed on Nov. 30, 2010, which is incorporated herein by reference.

TECHNICAL FIELD

The present disclosure relates generally to the field of semiconductor devices, and more particularly, to methods of forming integrated circuits.

BACKGROUND

The semiconductor integrated circuit (IC) industry has experienced rapid growth. Technological advances in IC materials and design have produced generations of ICs where each generation has smaller and more complex circuits than the previous generation. However, these advances have increased the complexity of processing and manufacturing ICs and, for these advances to be realized, similar developments in IC processing and manufacturing are needed.

In the course of IC evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometry size (i.e., the smallest component (or line) that can be created using a fabrication process) has decreased. This scaling down process generally provides benefits by increasing production efficiency and lowering associated costs. Such scaling-down also produces a relatively high power dissipation value, which may be addressed by using low power dissipation devices such as complementary metal-oxide-semiconductor (CMOS) devices.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale and are used for illustration purposes only. In fact, the numbers and dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIG. 1 is a flowchart illustrating an exemplary method of forming an integrated circuit in accordance with some embodiments.

FIGS. 2A-2G are schematic cross-sectional views of an integrated circuit during various fabrication stages according to the method depicted in FIG. 1.

FIG. 3 is a flowchart illustrating another exemplary method of forming an integrated circuit in accordance with some embodiments.

FIGS. 4A-4E are schematic cross-sectional views of an integrated circuit during various fabrication stages according to the method depicted in FIG. 3.

FIG. 5 is a schematic drawing illustrating an exemplary apparatus for a pulsed plasma doping (PLAD) process.

DETAILED DESCRIPTION

Generally, a plurality of ion implantations have been implemented for forming source/drain (S/D) regions, lightly-doped drain (LDD) regions, and pocket regions of transistors. For example, an N-type source/drain (NSD) process has a phosphorus ion implantation that is provided to form a gradient dopant junction profile in a substrate. A carbon ion implantation is then performed to the S/D regions to prevent over diffusion of phosphorus dopants into the substrate. An arsenic ion implantation and a phosphorus implantation are performed to form S/D doped regions. After the multiple ion implantations, a rapid thermal anneal (RTA) is performed to activate dopants and cure damage resulting from the ion implantations. Silicide is then formed at the top of the S/D doped regions.

As noted, the process described above uses the phosphorus ion implantation to form the junction profile. When transistors are scaling down, the S/D junction profile may be too deep. The multiple ion implantations may also substantially damage the S/D regions. To cure the damage, a high thermal budget, e.g., a higher RTA temperature of about 1050° C. and/or a longer RTA time, may be applied. The high thermal budget may aggravate short-channel effect (SCE) of the transistors. If a low thermal budget is applied, implantation damage may not be desirably cured. Thus, the subsequent thermal budget may also result in a transient-enhanced diffusion (TED).

One of the key issues of scaling down CMOS is how to optimize the LDD junction in order to alleviate the short channel effect (SCE). Ion implantation through a dielectric layer is widely utilized to minimize the implanted defects. However, in those technologies, end-of-range defects are intrinsic, so the device performance such as SCE is degraded. In addition, the shadow effect resulting from the pitch reduction is undesired.

It is understood that the following descriptions provides many different embodiments, or examples, for implementing different features of the disclosure. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. Moreover, the formation of a feature on, connected to, and/or coupled to another feature in the present disclosure that follows may include embodiments in which the features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the features, such that the features may not be in direct contact. In addition, spatially relative terms, for example, “lower,” “upper,” “horizontal,” “vertical,” “above,” “below,” “up,” “down,” “top,” “bottom,” etc. as well as derivatives thereof (e.g., “horizontally,” “downwardly,” “upwardly,” etc.) are used for ease of the present disclosure of one features relationship to another feature. The spatially relative terms are intended to cover different orientations of the device including the features.

Illustrated in FIG. 1 is a flowchart of an exemplary method of forming an integrated circuit. FIGS. 2A-2G are schematic cross-sectional views of an integrated circuit during various fabrication stages. The integrated circuit may include various passive and active microelectronic devices, such as resistors, capacitors, inductors, diodes, metal-oxide-semiconductor field effect transistors (MOSFET), complementary MOS (CMOS) transistors, bipolar junction transistors (BJT), laterally diffused MOS (LDMOS) transistors, high power MOS transistors, FinFET transistors, or other types of transistors. It is understood that FIGS. 2A-2G have been simplified for a better understanding of the concepts of the present disclosure. Accordingly, it should be noted that additional processes may be provided before, during, and after the method 100 of FIG. 1, and that some other processes may only be briefly described herein.

Referring now to FIG. 1, the method 100 can include forming a gate structure over a substrate (block 110). The method 100 can include removing portions of the substrate to form recesses adjacent to the gate structure (block 120). The method 100 can include forming a dopant-rich layer having first type dopants on a sidewall and a bottom of each of the recesses (block 130). The method 100 can also include forming a silicon-containing material structure in each of the recesses (block 140). The silicon-containing material structure has second type dopants. The second type dopants are opposite to the first type dopants. In some embodiments, the first and second type dopants can each be electron donors or electron acceptors.

Referring now to FIGS. 2A-2G in conjunction with FIG. 1, an integrated circuit 200 can be fabricated in accordance with the method 100 of FIG. 1. In FIG. 2A, the integrated circuit 200 can have a substrate 201. In some embodiments, the substrate 201 can be a silicon substrate doped with dopants, such as boron, arsenic, or phosphorus. In other embodiments, the substrate 201 may alternatively be made of some other suitable elementary semiconductor, such as diamond or germanium; a suitable compound semiconductor, such as silicon carbide, silicon germanium, indium arsenide, or indium phosphide; or a suitable alloy semiconductor, such as silicon germanium carbide, gallium arsenic phosphide, or gallium indium phosphide. Further, the substrate 201 could include an epitaxial layer (epi layer), may be strained for performance enhancement, and may include a silicon-on-insulator (SOI) structure.

In some embodiments, shallow trench isolation (STI) features 210 a and 210 b may be formed in the substrate 201. The STI features 210 a and 210 b are formed by etching recesses (or trenches) in the substrate 201 and filling the recesses with a dielectric material. In some embodiments, the dielectric material of the STI features 210 a and 210 b includes silicon oxide. In some alternative embodiments, the dielectric material of the STI features 210 a and 210 b may include silicon nitride, silicon oxy-nitride, fluoride-doped silicate (FSG), a low-k dielectric material, other dielectric materials, or any combinations thereof.

Referring again to FIG. 2A, a gate structure 203 can be formed over a surface 201 a of the substrate 201. In some embodiments forming an N-type transistor, the integrated circuit 200 can include source/drain (S/D) regions, e.g., S/D regions 207 a and 207 b, adjacent to sidewalls of the gate structure 203. In some embodiments, the gate structure 203 can be a conductive gate structure, e.g., a polysilicon gate structure, a metal gate structure, a dummy gate structure, or any suitable gate structure. For example, a conductive gate structure can have a stack structure including a gate dielectric layer, a conductive material layer, and/or other suitable layers. A metal gate structure can have a stack structure including a high dielectric constant gate layer, a diffusion barrier layer, a metal work function layer, a metallic layer, and/or other suitable layers. A dummy gate structure can have a stack structure including a dummy material layer, a hard mask layer, and/or other suitable layers.

Referring to FIGS. 1 and 2B, the method 100 can include removing portions of the substrate to form recesses adjacent to the gate structure (block 120). For example, recesses 208 a and 208 b are formed in the substrate 201 and adjacent to the gate structure 203 as shown in FIG. 2B. In some embodiments, spacers 211 a and 211 b can be formed on the sidewalls of the gate structure 203. The recesses 208 a and 208 b can be adjacent to the spacers 211 a and 211 b, respectively. In some embodiments, the spacers 211 a and 211 b can be made of at least one material, such as silicon nitride, silicon oxynitride, silicon carbide, silicon oxycarbide, other spacer materials, or any combinations thereof. In some embodiments, the spacers 211 a and 211 b can be referred to as offset spacers.

Referring to FIGS. 1 and 2C-2D, the method 100 can include forming a dopant-rich layer having first type dopants on a sidewall and a bottom of each of the recesses (block 130). For example, the block 130 can include forming a dopant-rich layer 215 that can be substantially conformally deposited over the recesses 208 a-208 b and the gate structure 203 as shown in FIG. 2C. The dopant-rich layer 215 can continuously extend on the spacers 211 a, 211 b, the gate structure 203 and the sidewalls and the bottom of each of the recesses 208 a and 208 b. In some embodiments, the dopant-rich layer 215 can be formed by a pulsed plasma doping (PLAD) process or a sub-atmospheric chemical vapor deposition (SACVD) process.

In some embodiments using a PLAD process, the dopant-rich layer 215 can be formed in an apparatus 500 shown in FIG. 5. In some embodiments, the apparatus 500 can include a chamber 502, in which the substrate 201 (FIG. 2A) is placed. The apparatus 500 can include power sources 504 and 506 that are electrically coupled with electrodes (not labeled) that are disposed in the chamber 502. In some embodiments, the power source 504 can be a radio frequency (RF) power source with a programmable pulse modulation function. The power source 506 can be a pulsed direct current (DC) or RF power source for providing a bias voltage on the substrate 201. In some embodiments, the power sources 504 and 506 can be operated independently from each other. Each of the power sources 504 and 506 can be programmed to be independently powered on and off without affecting the other.

Referring again to FIG. 5, plasma 508 can be generated from a process gas in the chamber 502. The process gas can include at least one dopant gas such as arsine (AsH₃), diborane (B₂H₆), phosphine (PH₃), boron trifluoride (BF₃), other dopant gases, and/or any combinations thereof, and at least one dilution gas such as Xe, Ar, He, Ne, H₂, other dilution gases, and/or any combinations thereof, for forming a predetermined composition of dopant-rich layer 215. In some embodiments, the PLAD process can have a bias voltage substantially equal to or less than about 1.5 KeV, a pressure substantially equal to or larger than about 6 mTorr, and an inductively coupled plasma (ICP) power ranging from about 250 Watt to about 1 KWatt.

In some embodiments, the dopant-rich layer 215 can be referred to as an ion assisted deposition (IAD) layer. In some embodiments forming a halo doped structure, the dopant-rich layer 215 can comprise dopants that are used for doping the halo doped structure. Depending on the conductivity type of the FinFET, in some embodiments, the dopant-rich layer 215 comprises n-type dopants (impurities) or p-type dopants (impurities). In some embodiments forming an N-type FinFET, the dopant-rich layer 215 can comprise boron, indium, and/or other group III elements. In other embodiments forming a P-type FinFET, the dopant-rich layer 215 can comprise phosphorus, arsenic, and/or other group V elements. In some embodiments, the atomic percentage of the dopant in the dopant-rich layer 215 may be substantially equal to or greater than about 90%.

Referring to FIG. 2D, the method 100 can optionally include thermally driving dopants of the dopant-rich layer 215 into the sidewall and bottom of each of the recesses 208 a-208 b. The thermal driving process 220 can drive the dopants into the substrate 201 to form halo doped regions 215 a and 215 b.

In some embodiments, the method 100 can include removing at least a portion of the dopant-rich layer 215. For example, the dopant-rich layer 215 can be substantially completely removed as shown in FIG. 2E. In at least this embodiment, the halo doped regions 215 a and 215 b can be referred to as halo doped structures. In other embodiments, the portion of the dopant-rich layer 215 that is over the surface 201 a is removed. The remaining dopant-rich layer can continuously extend on the sidewalls and bottom of each of the recesses 208 a and 208 b. In at least this embodiment, the combination of the halo doped region 215 a and the remaining dopant-rich layer can be referred to as a halo doped structure.

Referring again to FIG. 1, the method 100 can include forming a silicon-containing material structure in each of the recesses (block 140). For example, silicon-containing material structures 213 a and 213 b can be formed in the recesses 208 a-208 b, respectively, as shown in FIG. 2F. The silicon-containing material structures 213 a-213 b each can have a dopant type that is opposite to that of the dopant-rich layer 215.

In some embodiments, the silicon-containing material structure 213 a can have an upper potion and a bottom portion (not labeled). The upper portion can be adjacent to the surface 201 a of the substrate. The bottom portion is farther away from the surface 201 a than the upper portion. The upper portion can have a dopant concentration which is higher than that of the bottom portion. In other embodiments, the silicon-containing material structure 213 a can have a dopant profile that gradually increases from the bottom portion to the upper potion. In yet other embodiments, the dopant concentration of the upper portion of the silicon-containing material structure 213 a can be higher than that of the halo doped region 215 a. In yet still other embodiments, the dopant concentration of the bottom potion of the silicon-containing material structure 213 a can be lower than that of the halo doped region 215 a.

In some embodiments, the silicon-containing material structures 213 a and 213 b can be formed by epitaxially depositing at least one silicon-containing material in the recesses 208 a and 208 b, respectively. Though the silicon-containing material structures 213 a and 213 b each show a single structure, the scope of this application is not limited thereto. In some embodiments, the silicon-containing material structures 213 a and 213 b each can be formed by multiple epitaxial depositions. The multiple epitaxial depositions each may have different dopant dosages.

In some embodiments forming an N-type transistor, the silicon-containing material structures 213 a and 213 b can be made of at least one material, such as silicon, silicon carbide, other semiconductor materials, and/or any combinations thereof. In other embodiments forming a P-type transistor, the silicon-containing material structures 213 a and 213 b can be made of at least one material, such as silicon, silicon germane, other semiconductor materials, and/or any combinations thereof.

In some embodiments, the silicon-containing material structures 213 a and 213 b can be formed by chemical vapor deposition (CVD), e.g., metalorganic CVD (MOCVD), low pressure CVD (LPCVD), atomic layer CVD (ALCVD), ultrahigh vacuum CVD (UHVCVD), reduced pressure CVD (RPCVD), any suitable CVD; molecular beam epitaxy (MBE) process; any suitable epitaxial process; or any combinations thereof.

In some embodiments, the deposition of the silicon-containing material structures 213 a and 213 b can include in-situ doping the silicon-containing material structures 213 a and 213 b. For example, forming an N-type transistor can use an N-type doping precursor, e.g., phosphine (PH₃) and/or other N-type doping precursor. By using the in-situ doping process, the dopant profile of the silicon-containing material structures 213 a and 213 b can be desirably achieved. In some embodiments, the silicon-containing material structures 213 a and 213 b can be an N-type doped silicon layer that is doped with phosphorus. The phosphorus-doped silicon layer can be referred to as a silicon phosphorus (SiP) layer.

In some embodiments, the method 100 can optionally include thermally driving dopants of the silicon-containing material structure into the sidewall and the bottom of each of the recesses. For example, a thermal driving process 230 can drive dopants of the silicon-containing material structures 213 a and 213 b into the sidewall and the bottom of each of the recesses 208 a-208 b as shown in FIG. 2G. In some embodiments, the dopant concentration of the upper potions of the silicon-containing material structures 213 a and 213 b can be higher than that of the halo doped regions 215 a and 215 b, respectively. The dopants of the upper portions of the silicon-containing material structures 213 a and 213 b can compensate the dopants of the halo doped regions 215 a and 215 b, respectively, at the regions that are adjacent to the surface 201 a so as to form lightly-doped drains (LDDs) 209 a and 209 b in the substrate 201. The LDDs 209 a and 209 b can have the same dopant type as the silicon-containing material structures 213 a and 213 b. In some embodiments, the LDDs 209 a and 209 b can be referred to as S/D extensions.

In some embodiments, the thermal driving process 230 can include a rapid thermal annealing (RTA) process. The RTA process can activate the dopants of the silicon-containing material structures 213 a and 213 b. In some embodiments, the RTA process can have a spike annealing temperature of about 1010° C. or lower. In some embodiments, silicide (not shown), e.g., nickel silicide, can be formed on the silicon-containing material structures 213 a and 213 b.

In some other embodiments, a remaining dopant-rich layer can be kept on the sidewalls and the bottom of each of the recesses 208 a-208 b as described above in conjunction with FIG. 2E. The thermal driving process 230 can drive dopants of the silicon-containing material structures 213 a and 213 b into the respective remaining dopant-rich layer.

As noted, the method 100 includes forming the dopant-rich layer and the silicon-containing material structure to form the halo doped regions, the LDDs, and the S/D doped regions. Since forming the dopant-rich layer and forming the silicon-containing material structure do not use any ion implantation process. Predetermined dopant profiles of the halo doped regions and the S/D doped regions can be achieved.

As also noted, the LDDs 209 a and 209 b are not formed by an ion implantation process. End-of-range defects resulting from ion implantation through a dielectric layer can be avoided. Yields impaired by the end-of-range defects can be reduced.

Illustrated in FIG. 3 is a flowchart of another exemplary method of forming an integrated circuit. FIGS. 4A-4E are schematic cross-sectional views of an integrated circuit during various fabrication stages. Items of FIGS. 4A-4E that are the same or similar items in FIGS. 2A-2F are indicated by the same reference numerals, increased by 200.

Referring now to FIG. 3, the method 300 can include forming a gate structure over a substrate (block 310). The method 300 can include removing portions of the substrate to form recesses adjacent to the gate structure (block 320). The method 300 can include epitaxially depositing a halo doped layer having first type dopants on sidewalls and a bottom of each of the recesses (block 330). The method 300 can also include epitaxially depositing a silicon-containing material structure over the halo doped layer in each of the recesses (block 340). The silicon-containing material structure has second type dopants. The second type dopants are opposite to the first type dopants.

Referring now to FIGS. 4A-4E in conjunction with FIG. 3, an integrated circuit 400 can be fabricated in accordance with the method 300 of FIG. 3. For example, a gate structure 403 can be formed over a substrate 401 as shown in FIG. 4A. STI features 410 a-410 b can be formed in the substrate 401. Referring to FIG. 4B, recesses 408 a and 408 b can be formed in the S/D regions 407 a and 407 b, respectively. Spacers 411 a and 411 b can be formed on sidewalls of the gate structure 403.

Referring to FIG. 3, the method 300 can include epitaxially depositing a halo doped layer having first type dopants on sidewalls and a bottom of each of the recesses (block 130). For example, halo doped layers 416 a and 416 b can be epitaxially deposited on sidewalls and a bottom of each of the recesses 408 a and 408 b, respectively, as shown in FIG. 4C. In some embodiments, the halo doped layers 416 a and 416 b can be selectively grown from exposure regions of the substrate 401. Due to the selective deposition, the halo doped layers 416 a and 416 b is not formed on the STI features 410 a-410 b and the spacers 411 a-411 b.

In some embodiments, the halo doped layers 416 a and 416 b can be formed by chemical vapor deposition (CVD), e.g., metalorganic CVD (MOCVD), low pressure CVD (LPCVD), atomic layer CVD (ALCVD), ultrahigh vacuum CVD (UHVCVD), reduced pressure CVD (RPCVD), any suitable CVD; molecular beam epitaxy (MBE) process; any suitable epitaxial process; or any combinations thereof.

In some embodiments, the deposition of the halo doped layers 416 a and 416 b can include in-situ doping the halo doped layers 416 a and 416 b. In some embodiments for forming an N-type transistor, the halo doped layers 416 a and 416 b can be in-situ doped with boron and/or other group III elements. In other embodiments for forming a P-type transistor, the halo doped layers 416 a and 416 b can be in-situ doped with phosphorus, arsenic, and/or other group V elements.

Referring again to FIG. 3, the method 300 can include epitaxially depositing a silicon-containing material structure over the halo doped layer in each of the recesses (block 340). For example, silicon-containing material structures 413 a and 413 b can be epitaxially deposited over the halo doped layers 416 a and 416 b, respectively, as shown in FIG. 4D. The silicon-containing material structures 413 a-413 b can each have a dopant type that is opposite to that of the halo doped layers 416 a and 416 b.

In some embodiments, the silicon-containing material structure 413 a can have an upper potion and a bottom portion (not labeled). The upper portion can be adjacent to the surface 401 a of the substrate 401. The bottom portion is farther away from the surface 401 a than the upper portion. The upper portion can have a dopant concentration which is higher than that of the bottom portion. In other embodiments, the silicon-containing material structure 413 a can have a dopant profile that gradually increases from the bottom portion to the upper potion. In yet other embodiments, the dopant concentration of the upper portion of the silicon-containing material structure 413 a can be higher than that of the halo doped layer 416 a. In yet still other embodiments, the dopant concentration of the bottom potion of the silicon-containing material structure 413 a can be lower than that of the halo doped layer 416 a.

Referring to FIG. 4E, the method 400 can optionally include thermally driving dopants of the silicon-containing material structure into the halo doped layers. For example, a thermal driving process 430 can drive dopants of the silicon-containing material structures 413 a and 413 b into the halo doped layers 416 a and 416 b as shown in FIG. 4E. The thermal driving process 430 can also drive dopants of the halo doped layers 416 a and 416 b into the substrate 401 to form the halo doped regions 415 a and 415 b.

In some embodiments, the dopant concentration of the upper potions of the silicon-containing material structures 413 a and 413 b can be higher than that of the halo doped layers 416 a and 416 b, respectively. The dopants of the upper portions of the silicon-containing material structures 413 a and 413 b can compensate the dopants of the halo doped layers 416 a and 416 b, respectively, at the regions that are adjacent to the surface 401 a so as to form lightly-doped drains (LDDs) 409 a and 409 b in the substrate 401. The LDDs 409 a and 409 b can have the same dopant type as the silicon-containing material structures 413 a and 413 b. In some embodiments, the LDDs 409 a and 409 b can be referred to as S/D extensions.

As also noted, the method 400 includes epitaxially depositing the halo doped layer and the silicon-containing material structure that serves as the S/D doped region. Since epitaxially depositing the halo doped layer and forming the silicon-containing material structure do not use any ion implantation process. Predetermined dopant profiles of the halo doped layer and the S/D doped region can be achieved.

As noted, the processes of the methods 100 and 300 described above in conjunction with FIGS. 1 and 3 are merely exemplary. The methods 100 and 300 can each include different steps according to different process flows. For example, the gate structures 203 and 403 can each be formed by a gate-first process or a gate-last process. In some embodiments using a gate-last process, the methods 100 and 300 can each include a gate replacing process. The gate structures 203 and 403 can each be a dummy gate structure. The dummy gate structure can include a dummy gate material and a hard mask material formed thereover. The dummy gate material can be made of at least one material such as polysilicon, amorphous silicon, silicon oxide, silicon nitride, or a material having an etching rate that is substantially different from the spacers.

For the gate-last process, the hard mask materials and the dummy gate materials can be removed, for example, by a wet etch process, a dry etch process, or any combinations thereof. After removing the dummy gate materials, the methods 100 and 300 can each include forming gate electrode material within openings in which the dummy gate materials are disposed. In some embodiments, the gate electrode material can be a stack structure including a diffusion barrier layer, a metallic work function layer, a metallic conductive layer, and/or other suitable material layers.

In some embodiments, at least one high dielectric constant (high-k) layer (not shown) can be formed under the gate electrode material. The high-k dielectric layer can include high-k dielectric materials such as HfO₂, HfSiO, HfSiON, HfTaO, HfSiO, HfZrO, other suitable high-k dielectric materials, or any combinations thereof. In some embodiments, the high-k material may further be selected from metal oxides, metal nitrides, metal silicates, transition metal-oxides, transition metal-nitrides, transition metal-silicates, oxynitrides of metals, metal aluminates, zirconium silicate, zirconium aluminate, silicon oxide, silicon nitride, silicon oxynitride, zirconium oxide, titanium oxide, aluminum oxide, hafnium dioxide-alumina alloy, other suitable materials, or any combinations thereof.

In some embodiments, the diffusion barrier can be configured to prevent metallic ions of the work function metal material from diffusing into the gate dielectric material. The diffusion barrier may comprise at least one material such as aluminum oxide, aluminum, aluminum nitride, titanium, titanium nitride (TiN), tantalum, tantalum nitride, other suitable material, and/or combinations thereof.

In some embodiments, the metallic work function layer can include at least one P-metal work function layer and/or at least one N-metal work function layer. The P-type work function materials can include one or more of ruthenium, palladium, platinum, cobalt, nickel, and conductive metal oxides, and/or other suitable materials. The N-type metal materials can include one or more of hafnium, zirconium, titanium, tantalum, aluminum, metal carbides (e.g., hafnium carbide, zirconium carbide, titanium carbide, aluminum carbide), aluminides, and/or other suitable materials. In some embodiments, the metallic conductive layer can be made of at least one material, such as aluminum, copper, Ti, TiN, TaN, Ta, TaC, TaSiN, W, WN, MoN, MoON, RuO₂, and/or other suitable materials.

In some embodiments, dielectric materials, contact plugs, via plugs, metallic regions, and/or metallic lines (not shown) can be formed over the gate electrode portions for interconnection. The dielectric layers may include materials such as silicon oxide, silicon nitride, silicon oxynitride, low-k dielectric material, ultra low-k dielectric material, or any combinations thereof. The via plugs, metallic regions, and/or metallic lines can include materials such as tungsten, aluminum, copper, titanium, tantalum, titanium nitride, tantalum nitride, nickel silicide, cobalt silicide, other proper conductive materials, and/or combinations thereof. The via plugs, metallic regions, and/or metallic lines can be formed by any suitable processes, such as deposition, photolithography, and etching processes, and/or combinations thereof.

In a first exemplary embodiment, a method of forming an integrated circuit includes forming a gate structure over a substrate. Portions of the substrate are removed to form recesses adjacent to the gate structure. A dopant-rich layer having first type dopants is formed on a sidewall and a bottom of each of the recesses. A silicon-containing material structure is formed in each of the recesses. The silicon-containing material structure has second type dopants. The second type dopants are opposite to the first type dopants.

In a second exemplary embodiment, a method of forming an integrated circuit includes forming a gate structure over a substrate. Portions of the substrate are removed to form recesses adjacent to the gate structure. A halo doped layer having first type dopants is epitaxially deposited on a sidewall and a bottom of each of the recesses. A silicon-containing material structure is epitaxially deposited over the halo doped layer in each of the recesses. The silicon-containing material structure has second type dopants. The second type dopants are opposite to the first type dopants.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

1. A method of forming an integrated circuit, the method comprising: forming a gate structure over a substrate; removing portions of the substrate to form recesses adjacent to the gate structure; after the formation of the recesses, forming a dopant-rich layer having first type dopants on a sidewall and a bottom of each of the recesses; forming a silicon-containing material structure in each of the recesses, the silicon-containing material structure having second type dopants, and the second type dopants being opposite to the first type dopants; and driving the second type dopants into the substrate beyond the sidewalls of the recesses to form lightly-doped drains under the gate structure.
 2. The method of claim 1, wherein forming the dopant-rich layer comprises a pulsed plasma doping (PLAD) process or a sub-atmospheric chemical vapor deposition (SACVD) process.
 3. The method of claim 1, further comprising: thermally driving the first type dopants into the sidewall and the bottom of each of the recesses.
 4. The method of claim 3, further comprising: after the thermal driving process, removing the dopant-rich layer.
 5. The method of claim 4, further comprising: thermally driving the second type dopants into the sidewall and the bottom of each of the recesses to form a halo doped region.
 6. The method of claim 5, wherein the silicon-containing material structure has a top portion and a bottom portion, the top portion is adjacent to a surface of the substrate, and the top portion has a dopant concentration which is higher than that of the bottom portion.
 7. The method of claim 6, wherein the dopant concentration of the top portion is higher than that of the halo doped region.
 8. The method of claim 1, wherein forming the dopant-rich layer having first type dopants on the sidewall and the bottom of each of the recesses comprises: forming the dopant-rich layer continuously extending on a surface of the substrate, and the sidewall and the bottom of each of the recesses; and removing a portion of the dopant-rich layer that is on the surface of the substrate.
 9. The method of claim 8, further comprising: thermally driving the second type dopants into the remaining dopant-rich layer.
 10. The method of claim 1, wherein forming the silicon-containing material structure comprises: epitaxially depositing at least one silicon-containing material in each of the recesses.
 11. The method of claim 1, wherein the dopant-rich layer is provided to form a halo doped region and the silicon-containing material structure is provided to form a source/drain doped region.
 12. A method of forming an integrated circuit, the method comprising: forming a gate structure over a substrate; removing portions of the substrate to form recesses adjacent to the gate structure; after the formation of the recesses, forming a dopant-rich layer on a sidewall and a bottom of each of the recesses; driving the first type dopants of the dopant-rich layer into the sidewall and the bottom of each of the recesses; removing the dopant-rich layer after thermally driving the first type dopants; forming a silicon-containing material structure in each of the recesses, the silicon-containing material structure having second type dopants, and the second type dopants being opposite to the first type dopants; and driving the second type dopants into the substrate beyond the sidewalls of the recesses to form lightly-doped drains under the gate structure.
 13. The method of claim 12, wherein forming the dopant-rich layer comprises a pulsed plasma doping (PLAD) process or a sub-atmospheric chemical vapor deposition (SACVD) process.
 14. The method of claim 12, further comprising: thermally driving the second type dopants into the sidewall and the bottom of each of the recesses to form a halo doped region.
 15. The method of claim 12, wherein the silicon-containing material structure has a top portion and a bottom portion, the top portion is adjacent to a surface of the substrate, and the top portion has a dopant concentration which is higher than that of the bottom portion.
 16. The method of claim 15, wherein the dopant concentration of the top portion is higher than that of a halo doped region.
 17. The method of claim 12, wherein forming the silicon-containing material structure comprises: epitaxially depositing at least one silicon-containing material in each of the recesses.
 18. The method of claim 12, wherein the dopant-rich layer is provided to form a halo doped region and the silicon-containing material structure is provided to form a source/drain doped region.
 19. A method of forming an integrated circuit, the method comprising: forming a gate structure over a substrate; removing portions of the substrate to form recesses adjacent to the gate structure; epitaxially depositing a halo doped layer having first type dopants on a sidewall and a bottom of each of the recesses; epitaxially depositing a silicon-containing material structure over the halo doped layer in each of the recesses, the silicon-containing material structure having second type dopants, and the second type dopants being opposite to the first type dopants; and driving the second type dopants into the substrate beyond the sidewalls of the recesses to form lightly-doped drains under the gate structure.
 20. The method of claim 19, further comprising: thermally driving the second type dopants into the halo doped layer. 